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Information card for entry 4068425
Preview
Coordinates | 4068425.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C74 H87 O6.5 P3 Rh |
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Calculated formula | C74 H87 O6.5 P3 Rh |
SMILES | O(CC)CC.c12c3cccc1O[P]1(Oc4c(c(c(cc4C(C)(C)C)C)C)c4c(O1)c(cc(c4C)C)C(C)(C)C)[Rh]2([P]1(Oc2c(c(c(cc2C(C)(C)C)C)C)c2c(O1)c(cc(c2C)C)C(C)(C)C)O3)[P](c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Rhodium Complexes with Pincer Diphosphite Ligands. Unusual Olefin in-Plane Coordination in Square-Planar Compounds† |
Authors of publication | Rubio, Miguel; Suárez, Andrés; del Río, Diego; Galindo, Agustín; Álvarez, Eleuterio; Pizzano, Antonio |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 2 |
Pages of publication | 547 |
a | 24.7253 ± 0.0009 Å |
b | 12.9836 ± 0.0004 Å |
c | 21.7178 ± 0.0006 Å |
α | 90° |
β | 99.008 ± 0.002° |
γ | 90° |
Cell volume | 6885.9 ± 0.4 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 5 |
Space group number | 5 |
Hermann-Mauguin space group symbol | C 1 2 1 |
Hall space group symbol | C 2y |
Residual factor for all reflections | 0.0814 |
Residual factor for significantly intense reflections | 0.0711 |
Weighted residual factors for significantly intense reflections | 0.1431 |
Weighted residual factors for all reflections included in the refinement | 0.1561 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.047 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4068425.html
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Users of the data should acknowledge the original authors of the
structural data.