Information card for entry 4068427

Structure parameters

• Formula: C144 H187 Cl5 N2 O12 P4 Rh2
• Calculated formula: C144 H187 Cl5 N2 O12 P4 Rh2
• Title of publication: Rhodium Complexes with Pincer Diphosphite Ligands. Unusual Olefin in-Plane Coordination in Square-Planar Compounds†
• Authors of publication: Rubio, Miguel; Suárez, Andrés; del Río, Diego; Galindo, Agustín; Álvarez, Eleuterio; Pizzano, Antonio
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 2
• Pages of publication: 547
• a: 12.6244 ± 0.0009 Å
• b: 18.5218 ± 0.0015 Å
• c: 18.85 ± 0.002 Å
• α: 106.614 ± 0.003°
• β: 108.221 ± 0.003°
• γ: 107.806 ± 0.002°
• Cell volume: 3614 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1011
• Residual factor for significantly intense reflections: 0.0706
• Weighted residual factors for significantly intense reflections: 0.201
• Weighted residual factors for all reflections included in the refinement: 0.2291
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No