Crystallography Open Database
- COD Home
- Accessing COD Data
- Add Your Data
- Documentation
Information card for entry 4068429
Preview
Coordinates | 4068429.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C56 H71 O6 P2 Rh |
---|---|
Calculated formula | C56 H71 O6 P2 Rh |
SMILES | [Rh]123([P]4(Oc5c2c(O[P]21Oc1c(cc(c(c1c1c(O2)c(cc(c1C)C)C(C)(C)C)C)C)C(C)(C)C)ccc5)Oc1c(cc(c(c1c1c(O4)c(cc(c1C)C)C(C)(C)C)C)C)C(C)(C)C)[CH2]=[CH2]3 |
Title of publication | Rhodium Complexes with Pincer Diphosphite Ligands. Unusual Olefin in-Plane Coordination in Square-Planar Compounds† |
Authors of publication | Rubio, Miguel; Suárez, Andrés; del Río, Diego; Galindo, Agustín; Álvarez, Eleuterio; Pizzano, Antonio |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 2 |
Pages of publication | 547 |
a | 10.4092 ± 0.0011 Å |
b | 18.8544 ± 0.0018 Å |
c | 26.636 ± 0.003 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 5227.6 ± 0.9 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 5 |
Space group number | 19 |
Hermann-Mauguin space group symbol | P 21 21 21 |
Hall space group symbol | P 2ac 2ab |
Residual factor for all reflections | 0.0421 |
Residual factor for significantly intense reflections | 0.0352 |
Weighted residual factors for significantly intense reflections | 0.0717 |
Weighted residual factors for all reflections included in the refinement | 0.0747 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.019 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4068429.html
All data in the COD and the database itself are dedicated to the
public domain and licensed under the
CC0
License
.
Users of the data should acknowledge the original authors of the
structural data.