Information card for entry 4068462

Structure parameters

• Chemical name: Di(η^5^-cyclopentadienyl)molybdenum-bis(bismuthdi(tert- butyldimethylsilanolat))
• Formula: C34 H70 Bi2 Mo O4 Si4
• Calculated formula: C34 H70 Bi2 Mo O4 Si4
• SMILES: [cH]12[cH]3[cH]4[cH]5[cH]1[Mo]167892345([cH]2[cH]8[cH]7[cH]6[cH]12)[Bi]([O]([Si](C)(C)C(C)(C)C)[Bi]9O[Si](C)(C)C(C)(C)C)(O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C
• Title of publication: Opening of Bent Bi−C Bonds by Silanols To Give Stable Cp2Mo(μ-BiOR)2MoCp2Complexes
• Authors of publication: Knispel, Christina; Limberg, Christian; Mehring, Michael
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 2
• Pages of publication: 646
• a: 10.8274 ± 0.0011 Å
• b: 12.1563 ± 0.0012 Å
• c: 34.104 ± 0.004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4488.8 ± 0.8 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.091
• Residual factor for significantly intense reflections: 0.0542
• Weighted residual factors for significantly intense reflections: 0.0901
• Weighted residual factors for all reflections included in the refinement: 0.0994
• Goodness-of-fit parameter for all reflections included in the refinement: 0.901
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No