Information card for entry 4068501

Structure parameters

• Common name: PtIVOH
• Chemical name: PtIVOH
• Formula: C41 H50 O3 P2 Pt
• Calculated formula: C41 H50 O3 P2 Pt
• SMILES: [Pt]1([P](c2c([P]1(c1ccccc1)c1ccccc1)cccc2)(c1ccccc1)c1ccccc1)(O)(C)(C)C.O1CCCC1.O1CCCC1
• Title of publication: Reductive Elimination and Dissociative β-Hydride Abstraction from Pt(IV) Hydroxide and Methoxide Complexes
• Authors of publication: Smythe, Nicole A.; Grice, Kyle A.; Williams, B. Scott; Goldberg, Karen I.
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 1
• Pages of publication: 277
• a: 16.0485 ± 0.0008 Å
• b: 16.657 ± 0.0005 Å
• c: 24.308 ± 0.0008 Å
• α: 90°
• β: 143.857 ± 0.0017°
• γ: 90°
• Cell volume: 3832.5 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0556
• Residual factor for significantly intense reflections: 0.0404
• Weighted residual factors for significantly intense reflections: 0.0896
• Weighted residual factors for all reflections included in the refinement: 0.1026
• Goodness-of-fit parameter for all reflections included in the refinement: 1.147
• Diffraction radiation wavelength: 0.71074 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No