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Information card for entry 4068655
Preview
Coordinates | 4068655.cif |
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Original paper (by DOI) | HTML |
Chemical name | Tetracarbonyl-[1-(1,3-dimesityl-terahydro-1,3,2-diazophospholenyl)- 2-(2',3',4',5'-tetraethylphospholyl)-1-imino-prop-1-en]-tungsten(0) |
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Formula | C38 H49 N3 O4 P2 W |
Calculated formula | C38 H49 N3 O4 P2 W |
SMILES | [W]1(C#[O])(C#[O])(C#[O])(C#[O])[P]2(N=C(C)[P]31C(=C(C(=C3CC)CC)CC)CC)N(CCN2c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C |
Title of publication | Cleavage of Polarized P−P Bonds in N-Heterocyclic Diphosphines in Reactions with Metal Olefin Complexes |
Authors of publication | Burck, Sebastian; Gudat, Dietrich; Nieger, Martin |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 5 |
Pages of publication | 1447 |
a | 14.568 ± 0.0001 Å |
b | 20.7786 ± 0.0001 Å |
c | 25.2384 ± 0.0002 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 7639.73 ± 0.09 Å3 |
Cell temperature | 123 ± 2 K |
Ambient diffraction temperature | 123 ± 2 K |
Number of distinct elements | 6 |
Space group number | 61 |
Hermann-Mauguin space group symbol | P b c a |
Hall space group symbol | -P 2ac 2ab |
Residual factor for all reflections | 0.0329 |
Residual factor for significantly intense reflections | 0.0237 |
Weighted residual factors for significantly intense reflections | 0.0573 |
Weighted residual factors for all reflections included in the refinement | 0.0599 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.038 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4068655.html
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Users of the data should acknowledge the original authors of the
structural data.