Information card for entry 4068911

Structure parameters

• Formula: C36 H47 Br N2 Si
• Calculated formula: C36 H47 Br N2 Si
• SMILES: Br[Si]1(N(C(=C)C=C(N1c1c(cccc1C(C)C)C(C)C)C)c1c(cccc1C(C)C)C(C)C)Cc1ccccc1
• Title of publication: Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes
• Authors of publication: Xiong, Yun; Yao, Shenglai; Driess, Matthias
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 6
• Pages of publication: 1927
• a: 8.7511 ± 0.0005 Å
• b: 12.1062 ± 0.0006 Å
• c: 16.5833 ± 0.0009 Å
• α: 109.092 ± 0.004°
• β: 97.563 ± 0.004°
• γ: 94.229 ± 0.004°
• Cell volume: 1632.96 ± 0.16 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0584
• Residual factor for significantly intense reflections: 0.0346
• Weighted residual factors for significantly intense reflections: 0.069
• Weighted residual factors for all reflections included in the refinement: 0.0735
• Goodness-of-fit parameter for all reflections included in the refinement: 0.907
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No