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Information card for entry 4069160
Preview
Coordinates | 4069160.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C45 H43 N2 O2 P2 Rh |
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Calculated formula | C45 H43 N2 O2 P2 Rh |
SMILES | [Rh]12(OC(=CC(=[O]2)C)C)[P]2([C@@H](CC[C@H]2c2ccccc2)c2ccccc2)c2nc3ccccc3nc2[P]21[C@@H](CC[C@H]2c1ccccc1)c1ccccc1 |
Title of publication | Bridging Group Effects in Chelating Bis(2,5-diphenylphospholane) Ligands for Rhodium-Catalyzed Asymmetric Hydroformylation |
Authors of publication | Axtell, Alex T.; Klosin, Jerzy; Whiteker, Gregory T.; Cobley, Christopher J.; Fox, Martin E.; Jackson, Mark; Abboud, Khalil A. |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 10 |
Pages of publication | 2993 |
a | 13.6719 ± 0.0011 Å |
b | 15.5546 ± 0.0013 Å |
c | 17.9798 ± 0.0015 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 3823.6 ± 0.5 Å3 |
Cell temperature | 173 ± 2 K |
Ambient diffraction temperature | 173 ± 2 K |
Number of distinct elements | 6 |
Space group number | 19 |
Hermann-Mauguin space group symbol | P 21 21 21 |
Hall space group symbol | P 2ac 2ab |
Residual factor for all reflections | 0.0379 |
Residual factor for significantly intense reflections | 0.0354 |
Weighted residual factors for significantly intense reflections | 0.0745 |
Weighted residual factors for all reflections included in the refinement | 0.0754 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.217 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4069160.html
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Users of the data should acknowledge the original authors of the
structural data.