Information card for entry 4069620

Structure parameters

• Formula: C163 H212 Cl2 O28 P4 Rh2
• Calculated formula: C163 H212 Cl2 O28 P4 Rh2
• Title of publication: TroposLigands in Asymmetric Rhodium(I)-Catalyzed Addition of Arylboronic Acids to Enones: How a Tunable Coordination Gives Different Reaction Products
• Authors of publication: Facchetti, Sarah; Cavallini, Irene; Funaioli, Tiziana; Marchetti, Fabio; Iuliano, Anna
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 14
• Pages of publication: 4150
• a: 17.987 ± 0.001 Å
• b: 27.32 ± 0.002 Å
• c: 31.536 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 15496.9 ± 1.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.054
• Residual factor for significantly intense reflections: 0.0528
• Weighted residual factors for significantly intense reflections: 0.1484
• Weighted residual factors for all reflections included in the refinement: 0.1506
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.70001 Å
• Diffraction radiation type: synchrotronradiation
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No