Information card for entry 4069725

Structure parameters

• Formula: C45 H62 N2 P Rh Si
• Calculated formula: C45 H62 N2 P Rh Si
• SMILES: [RhH2]1([Si](c2ccccc2)(c2ccccc2)c2ccccc2)([P](C(C)C)(C(C)C)C(C)C)[n]2c(cc(cc2)C(C)(C)C)c2[n]1ccc(c2)C(C)(C)C
• Title of publication: Synthesis and Reactivity of Iridium and Rhodium Silyl Complexes Supported by a Bipyridine Ligand
• Authors of publication: McBee, Jennifer L.; Tilley, T. Don
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 17
• Pages of publication: 5072
• a: 11.5573 ± 0.0011 Å
• b: 14.1086 ± 0.0013 Å
• c: 14.3656 ± 0.0013 Å
• α: 94.548 ± 0.001°
• β: 104.543 ± 0.001°
• γ: 109.81 ± 0.001°
• Cell volume: 2098.1 ± 0.3 ų
• Cell temperature: 151 ± 2 K
• Ambient diffraction temperature: 151 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0478
• Residual factor for significantly intense reflections: 0.0348
• Weighted residual factors for significantly intense reflections: 0.0799
• Weighted residual factors for all reflections included in the refinement: 0.0832
• Goodness-of-fit parameter for all reflections included in the refinement: 1.022
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No