X-ray Crystallographic and NMR Spectroscopic Study of (η2-Alkene)(μ-alkyne)pentacarbonyldicobalt Complexes: Arrested Pauson−Khand Reaction Intermediates
Authors of publication
Brusey, Sarah A.; Banide, Emilie V.; Dörrich, Steffen; O’Donohue, Paul; Ortin, Yannick; Müller-Bunz, Helge; Long, Conor; Evans, Paul; McGlinchey, Michael J.
Journal of publication
Organometallics
Year of publication
2009
Journal volume
28
Journal issue
21
Pages of publication
6308
a
11.5912 ± 0.0014 Å
b
13.8714 ± 0.0016 Å
c
8.0454 ± 0.0009 Å
α
90°
β
101.579 ± 0.002°
γ
90°
Cell volume
1267.3 ± 0.3 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
3
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0534
Residual factor for significantly intense reflections
0.0486
Weighted residual factors for significantly intense reflections
0.1286
Weighted residual factors for all reflections included in the refinement
0.1321
Goodness-of-fit parameter for all reflections included in the refinement