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Information card for entry 4070436
Preview
Coordinates | 4070436.cif |
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Original paper (by DOI) | HTML |
Formula | C14 H26 Cl2 N2 Si Ti |
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Calculated formula | C14 H26 Cl2 N2 Si Ti |
SMILES | [Ti]123456(N([Si]([c]73[c]4([c]5([c]6([c]72C)C)C)C)(C)C)CC[NH]1C)(Cl)Cl |
Title of publication | M−Cl/Si−Cl Preferential Reactivity in Chlorosilyl-Substituted Cyclopentadienyl Early Transition Metal Complexes in Reactions with Amines: Key to Understanding the Nature of the Final Product |
Authors of publication | Paniagua, Cristina; Mosquera, Marta E. G.; Jacobsen, Heiko; Jiménez, Gerardo; Cuenca, Tomás |
Journal of publication | Organometallics |
Year of publication | 2009 |
Journal volume | 28 |
Journal issue | 24 |
Pages of publication | 6975 |
a | 8.552 ± 0.003 Å |
b | 9.05 ± 0.005 Å |
c | 13.769 ± 0.006 Å |
α | 75.26 ± 0.03° |
β | 87.66 ± 0.04° |
γ | 62.91 ± 0.03° |
Cell volume | 914 ± 0.8 Å3 |
Cell temperature | 200 ± 2 K |
Ambient diffraction temperature | 200 ± 2 K |
Number of distinct elements | 6 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.1246 |
Residual factor for significantly intense reflections | 0.0866 |
Weighted residual factors for significantly intense reflections | 0.2225 |
Weighted residual factors for all reflections included in the refinement | 0.2423 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.086 |
Diffraction radiation wavelength | 0.71069 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4070436.html
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Users of the data should acknowledge the original authors of the
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