Information card for entry 4071201

Structure parameters

• Common name: complex 11
• Formula: C22 H39 F2 O4 P3 Rh
• Calculated formula: C22 H39 F2 O4 P3 Rh
• Title of publication: B−C Bond Cleavage of BArFAnion Upon Oxidation of Rhodium(I) with AgBArF. Phosphinite Rhodium(I), Rhodium(II), and Rhodium(III) Pincer Complexes
• Authors of publication: Salem, Hiyam; Shimon, Linda J. W.; Leitus, Gregory; Weiner, Lev; Milstein, David
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 10
• Pages of publication: 2293
• a: 8.404 ± 0.0017 Å
• b: 16.6 ± 0.003 Å
• c: 20.931 ± 0.004 Å
• α: 102.71 ± 0.03°
• β: 95.99 ± 0.03°
• γ: 104.26 ± 0.03°
• Cell volume: 2721.6 ± 1.1 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0791
• Residual factor for significantly intense reflections: 0.0461
• Weighted residual factors for significantly intense reflections: 0.1068
• Weighted residual factors for all reflections included in the refinement: 0.1182
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No