Information card for entry 4071233

Structure parameters

• Formula: C32 H50 O8 Os3 P2 Pt
• Calculated formula: C32 H50 O8 Os3 P2 Pt
• SMILES: [O]#C[Os]123([Os]456([Os]781([P]5(C(C)(C)C)C(C)(C)C)([CH]6([Pt]24([P](C(C)(C)C)(C(C)(C)C)C(C)(C)C)C#[O])[C]7(=[CH]38)C)(C#[O])C#[O])(C#[O])C#[O])(C#[O])C#[O]
• Title of publication: Cleavage oftert-Butyl Groups from the Tri-tert-butylphosphine Ligand in Osmium−Platinum Carbonyl Cluster Complexes
• Authors of publication: Adams, Richard D.; Boswell, Erin
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 9
• Pages of publication: 2021
• a: 9.1635 ± 0.0005 Å
• b: 25.1624 ± 0.0014 Å
• c: 17.6681 ± 0.001 Å
• α: 90°
• β: 101.637 ± 0.001°
• γ: 90°
• Cell volume: 3990.1 ± 0.4 ų
• Cell temperature: 294 ± 2 K
• Ambient diffraction temperature: 294 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0785
• Residual factor for significantly intense reflections: 0.0451
• Weighted residual factors for significantly intense reflections: 0.0881
• Weighted residual factors for all reflections included in the refinement: 0.1164
• Goodness-of-fit parameter for all reflections included in the refinement: 1.055
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No