Information card for entry 4071355

Structure parameters

• Formula: C19 H35 I P2 Pt Si
• Calculated formula: C19 H35 I P2 Pt Si
• SMILES: [Pt]1(I)([P](C)(C)CC[P]1(C)C)(C#C[Si](C)(C)C)(C)c1ccc(cc1)C
• Title of publication: Synthesis and Reactivity of (η1-Alkynyl)diorganoplatinum(IV) Species, Including Structural Studies of PtIMe(p-Tol)(CCSiMe3)(dmpe) [dmpe = 1,2-bis(dimethylphosphino)ethane] and the Platinum(II) Reagent PtPh2(dmpe)
• Authors of publication: Canty, Allan J.; Watson, Russell P.; Karpiniec, Samuel S.; Rodemann, Thomas; Gardiner, Michael G.; Jones, Roderick C.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 13
• Pages of publication: 3203
• a: 16.982 ± 0.01 Å
• b: 10.492 ± 0.005 Å
• c: 15.289 ± 0.012 Å
• α: 90°
• β: 113.21 ± 0.08°
• γ: 90°
• Cell volume: 2504 ± 3 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1569
• Residual factor for significantly intense reflections: 0.0713
• Weighted residual factors for significantly intense reflections: 0.1697
• Weighted residual factors for all reflections included in the refinement: 0.2113
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No