Information card for entry 4071406

Structure parameters

• Formula: C41 H51 P Rh Si4
• Calculated formula: C41 H51 P Rh Si4
• Title of publication: “Synergistic Effects of Two Si−H Groups and a Metal Center” in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene
• Authors of publication: Sunada, Yusuke; Fujimura, Yoshiki; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 14
• Pages of publication: 3502
• a: 9.5341 ± 0.0013 Å
• b: 38.073 ± 0.004 Å
• c: 12.292 ± 0.0015 Å
• α: 90°
• β: 110.462 ± 0.005°
• γ: 90°
• Cell volume: 4180.4 ± 0.9 ų
• Cell temperature: 153.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0788
• Weighted residual factors for all reflections included in the refinement: 0.222
• Goodness-of-fit parameter for all reflections included in the refinement: 1.001
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No