Information card for entry 4071487

Structure parameters

• Formula: C43 H44 O5 P2 W
• Calculated formula: C43 H44 O5 P2 W
• SMILES: [W]([P]1(P(C1=C(c1ccccc1)c1ccccc1)c1c(cc(cc1C(C)(C)C)C(C)(C)C)C(C)(C)C)c1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Diastereoselective Formation of Complexed Methylenediphosphiranes
• Authors of publication: Jansen, Helen; Rosenthal, Amos J.; Slootweg, J. Chris; Ehlers, Andreas W.; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 12
• Pages of publication: 2868
• a: 11.3216 ± 0.0004 Å
• b: 13.2755 ± 0.0004 Å
• c: 14.5331 ± 0.0003 Å
• α: 70.009 ± 0.001°
• β: 78.96 ± 0.002°
• γ: 75.101 ± 0.001°
• Cell volume: 1970.75 ± 0.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0181
• Residual factor for significantly intense reflections: 0.0149
• Weighted residual factors for significantly intense reflections: 0.0317
• Weighted residual factors for all reflections included in the refinement: 0.0324
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No