Information card for entry 4071721

Structure parameters

• Formula: C11 H16 N2 O2 Si W
• Calculated formula: C11 H16 N2 O2 Si W
• SMILES: [W]1234(N=NC[Si](C)(C)C)([cH]5[cH]1[cH]2[cH]3[cH]45)(C#[O])C#[O]
• Title of publication: Kinetic and Thermodynamic Studies of the Reactivity of (Trimethylsilyl)diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo−N2CH2SiMe3Bond Strength and Experimental Determination of the Enthalpy of Formation of (Trimethylsilyl)diazomethane
• Authors of publication: Fortman, George C.; Isrow, Derek; McDonough, James E.; Schleyer, Paul von Ragué; Schaefer, Henry F.; Scott, Brian; Kubas, Gregory J.; Kégl, Tamás; Ungváry, Ferenc; Hoff, Carl D.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 19
• Pages of publication: 4873
• a: 6.3928 ± 0.0007 Å
• b: 10.6551 ± 0.0012 Å
• c: 10.8766 ± 0.0012 Å
• α: 100.632 ± 0.002°
• β: 96.245 ± 0.002°
• γ: 93.51 ± 0.002°
• Cell volume: 721.32 ± 0.14 ų
• Cell temperature: 203 ± 2 K
• Ambient diffraction temperature: 203 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0326
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0752
• Weighted residual factors for all reflections included in the refinement: 0.0764
• Goodness-of-fit parameter for all reflections included in the refinement: 1.114
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No