Information card for entry 4071800

Structure parameters

• Formula: C45 H30 Cl4 N2 O4 Rh4 S2
• Calculated formula: C45 H29 Cl4 N2 O4 Rh4 S2
• Title of publication: Ruthenium and Rhodium Complexes with Thiolate-Containing Pincer Ligands Produced by C−S Bond Cleavage of Pyridyl-Substituted Dibenzothiophenes
• Authors of publication: Shibue, Mayuko; Hirotsu, Masakazu; Nishioka, Takanori; Kinoshita, Isamu
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 17
• Pages of publication: 4475
• a: 10.4989 ± 0.0011 Å
• b: 15.479 ± 0.002 Å
• c: 15.746 ± 0.002 Å
• α: 77.245 ± 0.014°
• β: 70.566 ± 0.013°
• γ: 70.183 ± 0.013°
• Cell volume: 2253.3 ± 0.5 ų
• Cell temperature: 193.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0568
• Weighted residual factors for all reflections included in the refinement: 0.1202
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No