Information card for entry 4071803

Structure parameters

• Formula: C56 H51 N4 Rh
• Calculated formula: C56 H43 N4 Rh
• Title of publication: Base-Promoted Carbon−Hydrogen Bond Activation of Alkanes with Rhodium(III) Porphyrin Complexes
• Authors of publication: Chan, Yun Wai; Chan, Kin Shing
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 18
• Pages of publication: 4625
• a: 10.578 ± 0.002 Å
• b: 14.574 ± 0.003 Å
• c: 16.226 ± 0.004 Å
• α: 65.745 ± 0.004°
• β: 77.764 ± 0.004°
• γ: 82.348 ± 0.004°
• Cell volume: 2225.9 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0616
• Residual factor for significantly intense reflections: 0.0449
• Weighted residual factors for significantly intense reflections: 0.1124
• Weighted residual factors for all reflections included in the refinement: 0.1245
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No