Information card for entry 4071852

Structure parameters

• Common name: 12c
• Formula: C31 H40 N4 O2 Si
• Calculated formula: C31 H40 N4 O2 Si
• SMILES: [Si]123(OC(=N[N]2=C2CCCCCC2C2(N3N=C(O1)Cc1ccccc1)CCCCCC2)Cc1ccccc1)C
• Title of publication: Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
• Authors of publication: Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 20
• Pages of publication: 5285
• a: 9.691 ± 0.002 Å
• b: 11.134 ± 0.002 Å
• c: 14.777 ± 0.003 Å
• α: 80.57 ± 0.02°
• β: 89.28 ± 0.02°
• γ: 68.48 ± 0.02°
• Cell volume: 1461.3 ± 0.5 ų
• Cell temperature: 240 ± 1 K
• Ambient diffraction temperature: 240 ± 1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0602
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for significantly intense reflections: 0.1301
• Weighted residual factors for all reflections included in the refinement: 0.1395
• Goodness-of-fit parameter for all reflections included in the refinement: 0.859
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No