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Information card for entry 4071854
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Coordinates | 4071854.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | 15a |
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Chemical name | [N-(benzylideneimino)acetimidato-N',O] [N-(benzylamino)acetimidato-N',O]methylsilicon(IV) |
Formula | C19 H22 N4 O2 Si |
Calculated formula | C19 H22 N4 O2 Si |
SMILES | [Si]12(OC(=NN1Cc1ccccc1)C)(OC(=N[N]2=Cc1ccccc1)C)C |
Title of publication | Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation |
Authors of publication | Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel |
Journal of publication | Organometallics |
Year of publication | 2008 |
Journal volume | 27 |
Journal issue | 20 |
Pages of publication | 5285 |
a | 8.32 ± 0.002 Å |
b | 9.969 ± 0.002 Å |
c | 11.555 ± 0.002 Å |
α | 91.54 ± 0.02° |
β | 99.44 ± 0.03° |
γ | 90.17 ± 0.02° |
Cell volume | 945 ± 0.3 Å3 |
Cell temperature | 240 ± 2 K |
Ambient diffraction temperature | 240 ± 2 K |
Number of distinct elements | 5 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0615 |
Residual factor for significantly intense reflections | 0.0431 |
Weighted residual factors for significantly intense reflections | 0.1208 |
Weighted residual factors for all reflections included in the refinement | 0.1278 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.128 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/4071854.html
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Users of the data should acknowledge the original authors of the
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