Information card for entry 4071854

Structure parameters

• Common name: 15a
• Chemical name: [N-(benzylideneimino)acetimidato-N',O] [N-(benzylamino)acetimidato-N',O]methylsilicon(IV)
• Formula: C19 H22 N4 O2 Si
• Calculated formula: C19 H22 N4 O2 Si
• SMILES: [Si]12(OC(=NN1Cc1ccccc1)C)(OC(=N[N]2=Cc1ccccc1)C)C
• Title of publication: Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation
• Authors of publication: Kertsnus-Banchik, Evgenia; Kalikhman, Inna; Gostevskii, Boris; Deutsch, Zvicka; Botoshansky, Mark; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 20
• Pages of publication: 5285
• a: 8.32 ± 0.002 Å
• b: 9.969 ± 0.002 Å
• c: 11.555 ± 0.002 Å
• α: 91.54 ± 0.02°
• β: 99.44 ± 0.03°
• γ: 90.17 ± 0.02°
• Cell volume: 945 ± 0.3 ų
• Cell temperature: 240 ± 2 K
• Ambient diffraction temperature: 240 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0615
• Residual factor for significantly intense reflections: 0.0431
• Weighted residual factors for significantly intense reflections: 0.1208
• Weighted residual factors for all reflections included in the refinement: 0.1278
• Goodness-of-fit parameter for all reflections included in the refinement: 1.128
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No