Information card for entry 4071956

Structure parameters

• Formula: C60 H56 B2 F8 N2 Rh2
• Calculated formula: C60 H56 B2 F8 N2 Rh2
• SMILES: [B](F)(F)(F)[F-].c1(c2ccccc2ccc1N([c]12[cH]3[cH]4[cH]5[cH]6[cH]1[Rh]17823456[CH]2=[CH]8CC[CH]1=[CH]7CC2)c1ccccc1)c1c2ccccc2ccc1N([c]12[cH]3[cH]4[cH]5[cH]6[cH]1[Rh]17823456[CH]2=[CH]1CC[CH]7=[CH]8CC2)c1ccccc1.[B](F)(F)(F)[F-]
• Title of publication: Synthesis of Optically ActiveN,N,N′,N′-Tetraphenyl-1,1′-binaphthyl-2,2′-diamine Derivatives as Analogues of BINAP
• Authors of publication: Matsuzawa, Hiroshi; Tanabe, Yoshiaki; Miyake, Yoshihiro; Nishibayashi, Yoshiaki
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 15
• Pages of publication: 4021
• a: 13.8106 ± 0.0004 Å
• b: 13.8106 ± 0.0004 Å
• c: 26.083 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4974.9 ± 0.3 ų
• Cell temperature: 173.1 K
• Number of distinct elements: 6
• Space group number: 92
• Hermann-Mauguin space group symbol: P 41 21 2
• Hall space group symbol: P 4abw 2nw
• Residual factor for significantly intense reflections: 0.0459
• Weighted residual factors for all reflections included in the refinement: 0.1054
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No