Information card for entry 4072016

Structure parameters

• Formula: C37 H32 Cl2 N2 Pt Si
• Calculated formula: C37 H32 Cl2 N2 Pt Si
• SMILES: [Pt]123([N](=C(C=C(N1c1ccc(Cl)cc1)C)C)c1ccc(Cl)cc1)[CH2]=[CH]2[Si](c1ccccc1)(c1ccccc1)c1ccccc31
• Title of publication: Alkyne Insertion into the Pt−H Bond of Pt(H)(1-pentene)(β-diiminate) Initiates a Reaction Cascade That Results in C−H Activation or C−C Coupling
• Authors of publication: West, Nathan M.; White, Peter S.; Templeton, Joseph L.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 20
• Pages of publication: 5252
• a: 10.2345 ± 0.0002 Å
• b: 11.6447 ± 0.0002 Å
• c: 14.6854 ± 0.0003 Å
• α: 97.484 ± 0.001°
• β: 90.52 ± 0.001°
• γ: 91.588 ± 0.001°
• Cell volume: 1734.45 ± 0.06 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0314
• Residual factor for significantly intense reflections: 0.0274
• Weighted residual factors for significantly intense reflections: 0.0733
• Weighted residual factors for all reflections included in the refinement: 0.0751
• Goodness-of-fit parameter for all reflections included in the refinement: 1.101
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No