Information card for entry 4072142

Structure parameters

• Formula: C28 H32 P2 Pt S2 Si
• Calculated formula: C28 H32 P2 Pt S2 Si
• SMILES: c1(ccccc1)[P](C)(C)[Pt]1(S[Si](c2ccccc2)(c2ccccc2)S1)[P](c1ccccc1)(C)C
• Title of publication: Reactivity of Bis(silyl)platinum(II) Complexes toward Organic Isothiocyanates: Preparation and Structures of (Dithiocarbonimidato)- and (Diphenylsilanedithiolato)platinum(II) Complexes,cis-[Pt(S2CNPh)L2] andcis-[Pt(S2SiPh2)L2] (L = PMe2Ph, PEt3; L-L = dppp)
• Authors of publication: Lee, Kyung-Eun; Chang, Xiaohong; Kim, Yong-Joo; Huh, Hyun Sue; Lee, Soon W.
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 21
• Pages of publication: 5566
• a: 14.898 ± 0.002 Å
• b: 11.8386 ± 0.0009 Å
• c: 16.944 ± 0.004 Å
• α: 90°
• β: 106.882 ± 0.013°
• γ: 90°
• Cell volume: 2859.7 ± 0.8 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0262
• Residual factor for significantly intense reflections: 0.0223
• Weighted residual factors for significantly intense reflections: 0.0543
• Weighted residual factors for all reflections included in the refinement: 0.0564
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No