Information card for entry 4072572

Structure parameters

• Formula: C23 H37 N O S Si Ti
• Calculated formula: C23 H37 N O S Si Ti
• Title of publication: “Constrained Geometry” Titanium Complexes: Exceptionally Robust Systems for Living Polymerization of Methacrylates at High Temperature and Model Studies toward Chain Transfer Polymerization with Thiols
• Authors of publication: Lian, Bing; Thomas, Christophe M.; Navarro, Christophe; Carpentier, Jean-François
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 1
• Pages of publication: 187
• a: 14.7578 ± 0.0007 Å
• b: 15.198 ± 0.0007 Å
• c: 20.8733 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4681.7 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P c a b
• Hall space group symbol: -P 2bc 2ac
• Residual factor for all reflections: 0.0502
• Residual factor for significantly intense reflections: 0.0402
• Weighted residual factors for significantly intense reflections: 0.0991
• Weighted residual factors for all reflections included in the refinement: 0.1037
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No