Information card for entry 4072609

Structure parameters

• Formula: C43 H38 Cl2 N8 Pt
• Calculated formula: C43 H37 Cl2 N8 Pt
• SMILES: [Pt]1(C(=Nc2c(cccc2C)C)C(C(C1=Nc1c(cccc1C)C)(C#N)C#N)(C#N)C#N)(C#[N]c1c(cccc1C)C)C#[N]c1c(cccc1C)C.ClCCl
• Title of publication: Ring Expansion of a Platinacyclopropane to a Platinacyclopentane by Double Insertion of Isocyanides into Pt−C Bonds
• Authors of publication: Tsuchiya, Kazuhiro; Kondo, Hideo; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 4
• Pages of publication: 1044
• a: 13.507 ± 0.002 Å
• b: 43.455 ± 0.007 Å
• c: 15.453 ± 0.003 Å
• α: 90°
• β: 114.322 ± 0.0019°
• γ: 90°
• Cell volume: 8265 ± 2 ų
• Cell temperature: 123.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0602
• Weighted residual factors for all reflections included in the refinement: 0.1577
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No