Information card for entry 4072880

Structure parameters

• Formula: C24 H34 O P2 Pt
• Calculated formula: C24 H34 O P2 Pt
• SMILES: [Pt]1([P]2([C@@H](CC[C@H]2C)C)c2ccccc2[P]21[C@@H](CC[C@H]2C)C)(O)c1ccccc1
• Title of publication: Platinum-Catalyzed Asymmetric Alkylation of a Secondary Phosphine: Mechanism and Origin of Enantioselectivity
• Authors of publication: Scriban, Corina; Glueck, David S.; Golen, James A.; Rheingold, Arnold L.
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 7
• Pages of publication: 1788
• a: 8.434 ± 0.002 Å
• b: 13.588 ± 0.004 Å
• c: 20.825 ± 0.006 Å
• α: 90°
• β: 101.266 ± 0.006°
• γ: 90°
• Cell volume: 2340.6 ± 1.1 ų
• Cell temperature: 208 ± 2 K
• Ambient diffraction temperature: 208 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0448
• Weighted residual factors for significantly intense reflections: 0.1002
• Weighted residual factors for all reflections included in the refinement: 0.1018
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No