Information card for entry 4072961

Structure parameters

• Formula: C35 H57 B F4 O2 Os P2
• Calculated formula: C35 H47 B F4 O2 Os P2
• Title of publication: Hydride-Carbyne to Carbene Transformation in an Osmium-Acetate-Bis(triisopropylphosphine) System: Influence of the Coordination Mode of the Carboxylate and the Reaction Solvent
• Authors of publication: Bolaño, Tamara; Castarlenas, Ricardo; Esteruelas, Miguel A.; Oñate, Enrique
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 8
• Pages of publication: 2037
• a: 18.12 ± 0.003 Å
• b: 8.7037 ± 0.0015 Å
• c: 24.177 ± 0.004 Å
• α: 90°
• β: 104.984 ± 0.003°
• γ: 90°
• Cell volume: 3683.3 ± 1.1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0448
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0792
• Weighted residual factors for all reflections included in the refinement: 0.0821
• Goodness-of-fit parameter for all reflections included in the refinement: 0.906
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No