Information card for entry 4073246

Structure parameters

• Formula: C46 H48 Ag4 F24 N16 P4
• Calculated formula: C42 H42 Ag4 F24 N14 P4
• SMILES: [P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].[Ag]1=C2N3CN4C5N(C=C4)Cc4[n]([Ag]([n]6c(CN7C(N(CN8C=1N(C=C8)Cc1[n]([Ag]([n]8c(CN2C=C3)cccc8)[N]#CC)cccc1)C=C7)=[Ag]=5)cccc6)[N]#CC)cccc4.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Synthesis, Structural Characterization, and Luminescence of New Silver Aggregates Containing Short Ag−Ag Contacts Stabilized by Functionalized Bis(N-heterocyclic carbene) Ligands
• Authors of publication: Liu, Bin; Chen, Wanzhi; Jin, Shouwen
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 15
• Pages of publication: 3660
• a: 11.537 ± 0.002 Å
• b: 11.903 ± 0.002 Å
• c: 15.777 ± 0.003 Å
• α: 102.71 ± 0.003°
• β: 99.325 ± 0.003°
• γ: 109.119 ± 0.003°
• Cell volume: 1931.4 ± 0.6 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0621
• Residual factor for significantly intense reflections: 0.0375
• Weighted residual factors for significantly intense reflections: 0.089
• Weighted residual factors for all reflections included in the refinement: 0.0975
• Goodness-of-fit parameter for all reflections included in the refinement: 0.925
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No