Information card for entry 4073383

Structure parameters

• Formula: C61 H90 Li O4 Ti
• Calculated formula: C59.5 H60 Li O6 Ti
• Title of publication: Unexpected Binuclear Bis(phenolato) Titanium (IV) {[(L)Ti(Ph)]2(μ-OEt)2} Assisted by Carbon−Oxygen Bond Cleavage and Alkali-Metal-Containing Titanium(III) Complexes [Ti(L)2·M(solv)2] (M = Li, Na, K; solv = THF, DME)
• Authors of publication: Zhang, Dao
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 16
• Pages of publication: 4072
• a: 11.058 ± 0.005 Å
• b: 11.058 ± 0.005 Å
• c: 23.401 ± 0.011 Å
• α: 93.137 ± 0.008°
• β: 92.929 ± 0.009°
• γ: 100.721 ± 0.011°
• Cell volume: 2802 ± 2 ų
• Cell temperature: 173.1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.086
• Weighted residual factors for all reflections included in the refinement: 0.268
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No