Information card for entry 4073651

Structure parameters

• Formula: C28 H54 B F4 N Os P2
• Calculated formula: C28 H54 B F4 N Os P2
• Title of publication: Coordination and Rupture of Methyl C(sp3)−H Bonds in Osmium−Polyhydride Complexes with δ Agostic Interaction
• Authors of publication: Baya, Miguel; Eguillor, Beatriz; Esteruelas, Miguel A.; Lledós, Agustí; Oliván, Montserrat; Oñate, Enrique
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 21
• Pages of publication: 5140
• a: 8.5609 ± 0.0013 Å
• b: 11.7715 ± 0.0017 Å
• c: 17.222 ± 0.003 Å
• α: 77.477 ± 0.002°
• β: 79.399 ± 0.002°
• γ: 70.94 ± 0.002°
• Cell volume: 1589.3 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 373 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0366
• Residual factor for significantly intense reflections: 0.0284
• Weighted residual factors for significantly intense reflections: 0.0562
• Weighted residual factors for all reflections included in the refinement: 0.0575
• Goodness-of-fit parameter for all reflections included in the refinement: 0.949
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No