Information card for entry 4074305

Structure parameters

• Formula: C38 H31 N P Rh
• Calculated formula: C38 H31 N P Rh
• SMILES: [Rh]1234([N](c5ccccc5)=P(C15c1ccccc1c1ccccc15)(c1ccccc1)c1ccccc1)[CH]1=[CH]2C2[CH]3=[CH]4C1C2
• Title of publication: Enforced η1-Fluorenyl Coordination to Rhodium(I) with the [FluPPh2NPh]-Ligand
• Authors of publication: Freund, Christelle; Barros, Noémi; Gornitzka, Heinz; Martin-Vaca, Blanca; Maron, Laurent; Bourissou, Didier
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 20
• Pages of publication: 4927
• a: 9.6858 ± 0.0008 Å
• b: 11.6141 ± 0.001 Å
• c: 13.675 ± 0.0011 Å
• α: 106.982 ± 0.001°
• β: 94.884 ± 0.002°
• γ: 96.293 ± 0.002°
• Cell volume: 1451.2 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0505
• Residual factor for significantly intense reflections: 0.0353
• Weighted residual factors for significantly intense reflections: 0.0777
• Weighted residual factors for all reflections included in the refinement: 0.0835
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No