Information card for entry 4074314

Structure parameters

• Chemical name: tricarbonyl-tricyclohexylphosphino-tungsten(mu-carbonyl) (mu-bis(trimethylsilyl)aminoborylene)tricyclohexylphosphino-platinum
• Formula: C46 H84 B N O4 P2 Pt Si2 W
• Calculated formula: C46 H84 B N O4 P2 Pt Si2 W
• SMILES: [Pt]12([W]([P](C3CCCCC3)(C3CCCCC3)C3CCCCC3)(B1N([Si](C)(C)C)[Si](C)(C)C)(C2=O)(C#[O])(C#[O])C#[O])[P](C1CCCCC1)(C1CCCCC1)C1CCCCC1
• Title of publication: Synthesis and Reactivity of Semibridging Borylene Complexes
• Authors of publication: Braunschweig, Holger; Radacki, Krzysztof; Rais, Daniela; Uttinger, Katharina
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 21
• Pages of publication: 5159
• a: 12.1893 ± 0.0003 Å
• b: 13.438 ± 0.0004 Å
• c: 16.1074 ± 0.0004 Å
• α: 96.579 ± 0.001°
• β: 100.985 ± 0.001°
• γ: 96.473 ± 0.001°
• Cell volume: 2548.38 ± 0.12 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0247
• Residual factor for significantly intense reflections: 0.0225
• Weighted residual factors for significantly intense reflections: 0.057
• Weighted residual factors for all reflections included in the refinement: 0.0584
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No