Information card for entry 4074596

Structure parameters

• Formula: C51 H80 F3 O3.5 P5 Pt2 S
• Calculated formula: C51 H80 F3 O3.5 P5 Pt2 S
• SMILES: [Pt]1([P]2(c3c([P]41[C@@H](CC[C@H]4C)C)cccc3)[C@@H](CC[C@H]2C)C)([P]([Pt]1([P]2(c3ccccc3[P]31[C@@H](CC[C@H]3C)C)[C@@H](CC[C@H]2C)C)C)(c1ccccc1)CC(C)C)C.S(=O)(=O)([O-])C(F)(F)F.O1CCCC1
• Title of publication: Platinum(II) Phosphido Complexes as Metalloligands. Structural and Spectroscopic Consequences of Conversion from Terminal to Bridging Coordination
• Authors of publication: Scriban, Corina; Wicht, Denyce K.; Glueck, David S.; Zakharov, Lev N.; Golen, James A.; Rheingold, Arnold L.
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 14
• Pages of publication: 3370
• a: 13.001 ± 0.006 Å
• b: 13.676 ± 0.007 Å
• c: 18.526 ± 0.009 Å
• α: 82.144 ± 0.007°
• β: 71.255 ± 0.007°
• γ: 61.738 ± 0.006°
• Cell volume: 2747 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0778
• Residual factor for significantly intense reflections: 0.063
• Weighted residual factors for significantly intense reflections: 0.1462
• Weighted residual factors for all reflections included in the refinement: 0.1526
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No