Information card for entry 4074667

Structure parameters

• Formula: C38 H70 F12 P6 Rh2
• Calculated formula: C38 H70 F12 P6 Rh2
• Title of publication: P-Chiral Tetraphosphine Dirhodium Complex as a Catalyst for Asymmetric Hydrogenation: Synthesis, Structure, Enantioselectivity, and Mechanism. Stereoselective Formation of a Dirhodium Tetrahydride Complex and Its Reaction with Methyl (Z)-α-Acetamidocinnamate
• Authors of publication: Imamoto, Tsuneo; Yashio, Keiji; Crépy, Karen V. L.; Katagiri, Kosuke; Takahashi, Hidetoshi; Kouchi, Mitsuhiro; Gridnev, Ilya D.
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 4
• Pages of publication: 908
• a: 12.616 ± 0.001 Å
• b: 16.946 ± 0.002 Å
• c: 23.175 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4954.6 ± 0.8 ų
• Cell temperature: 150.2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections included in the refinement: 0.0961
• Goodness-of-fit parameter for all reflections included in the refinement: 1.566
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No