Information card for entry 4074725

Structure parameters

• Formula: C68 H58 O2 P2 Pt2 S2
• Calculated formula: C136 H116 O4 P4 Pt4 S4
• Title of publication: Reactions of α,β-Unsaturated Thioesters with Platinum(0): Implication of a Dual Mechanism Leading to the Formation of Acyl Platinum†
• Authors of publication: Minami, Yasunori; Kato, Tomohiro; Kuniyasu, Hitoshi; Terao, Jun; Kambe, Nobuaki
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 12
• Pages of publication: 2949
• a: 10.95 ± 0.001 Å
• b: 11.2767 ± 0.0008 Å
• c: 12.122 ± 0.001 Å
• α: 101.256 ± 0.003°
• β: 92.958 ± 0.004°
• γ: 103.578 ± 0.006°
• Cell volume: 1419.5 ± 0.2 ų
• Cell temperature: 223.2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0395
• Weighted residual factors for all reflections included in the refinement: 0.1056
• Goodness-of-fit parameter for all reflections included in the refinement: 1.758
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No