Information card for entry 4074806

Structure parameters

• Formula: C28 H26 N3 O2 P Rh2 Si
• Calculated formula: C28 H26 N3 O2 P Rh2 Si
• SMILES: [Rh]12([C]([Si](C)(C)C)#[C][Rh]3([n]4c(c5[n]3n2c(c5)C[P]1(c1ccccc1)c1ccccc1)cccc4)C#[O])C#[O]
• Title of publication: Synthesis of a Library of Iridium-Containing Dinuclear Complexes with Bridging PNNN and PNNP Ligands (BL), [LM(μ-BL)M'L']BF4. 2. Preparation, Basic Coordination Properties, and Reactivity of the Carbonyl Complexes
• Authors of publication: Dubs, Christian; Yamamoto, Toshiki; Inagaki, Akiko; Akita, Munetaka
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 6
• Pages of publication: 1359 - 1367
• a: 13.491 ± 0.008 Å
• b: 11.856 ± 0.003 Å
• c: 17.317 ± 0.01 Å
• α: 90°
• β: 102.72 ± 0.01°
• γ: 90°
• Cell volume: 2702 ± 2 ų
• Cell temperature: 213 K
• Ambient diffraction temperature: 213 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0711
• Weighted residual factors for all reflections included in the refinement: 0.2125
• Goodness-of-fit parameter for all reflections included in the refinement: 0.748
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No