Information card for entry 4074907

Structure parameters

• Formula: C93 H177 Cl6 Hf2 N4 O2 Si12
• Calculated formula: C93 H177 Cl6 Hf2 N4 O2 Si12
• Title of publication: Reduction of Tetravalent Group 4 Metal Complexes Supported by an Extremely Bulky, Unsymmetrically Substituted β-Diketiminato Ligand Leading to the Regioselective CN Bond Cleavage Giving Ring-Contracted Metal-Imido Complexes
• Authors of publication: Hamaki, Hirofumi; Takeda, Nobuhiro; Tokitoh, Norihiro
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 10
• Pages of publication: 2457
• a: 11.6597 ± 0.0001 Å
• b: 18.3005 ± 0.0002 Å
• c: 28.9162 ± 0.0003 Å
• α: 74.6796 ± 0.0008°
• β: 82.5888 ± 0.0004°
• γ: 77.1249 ± 0.0005°
• Cell volume: 5785.06 ± 0.1 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0242
• Residual factor for significantly intense reflections: 0.0204
• Weighted residual factors for significantly intense reflections: 0.0464
• Weighted residual factors for all reflections included in the refinement: 0.0477
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No