Information card for entry 4074939

Structure parameters

• Formula: C46 H58 F6 O8 P4 Pt2 S2
• Calculated formula: C46 H58 F6 O8 P4 Pt2 S2
• SMILES: C[P](C)(c1ccccc1)[Pt]2([OH][Pt]([P](C)(C)c1ccccc1)([OH]2)[P](C)(C)c1ccccc1)[P](C)(C)c1ccccc1.C(F)(F)(F)S(=O)(=O)[O-].c1ccccc1.C(F)(F)(F)S(=O)(=O)[O-].c1ccccc1
• Title of publication: Reaction Mechanism of Transmetalation between Tetraorganostannanes and Platinum(II) Aryltriflate Complexes. Mechanistic Model for Stille Couplings
• Authors of publication: Nilsson, Patrik; Puxty, Graeme; Wendt, Ola F.
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 5
• Pages of publication: 1285 - 1292
• a: 25.078 ± 0.005 Å
• b: 13.604 ± 0.003 Å
• c: 18.511 ± 0.004 Å
• α: 90°
• β: 110.12 ± 0.03°
• γ: 90°
• Cell volume: 5930 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.167
• Residual factor for significantly intense reflections: 0.0589
• Weighted residual factors for significantly intense reflections: 0.1155
• Weighted residual factors for all reflections included in the refinement: 0.1402
• Goodness-of-fit parameter for all reflections included in the refinement: 0.995
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No