Information card for entry 4074955

Structure parameters

• Formula: C23 H39 N O P Rh S2 W
• Calculated formula: C23 H39 N O P Rh S2 W
• SMILES: [W]123456([Rh]789%10(S1)(S2)([P](C)(C)C)[c]1([c]9([c]%10([c]7([c]81C)C)C)C)C)(N=O)[c]1([c]3([c]5([c]6([c]41C)C)C)C)C
• Title of publication: Electrophilic O-Methylation of a Terminal Nitrosyl Ligand Attained by an Early−Late Heterobimetallic Effect
• Authors of publication: Arashiba, Kazuya; Matsukawa, Shoji; Kuwata, Shigeki; Tanabe, Yoshiaki; Iwasaki, Masakazu; Ishii, Youichi
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 3
• Pages of publication: 560
• a: 17.008 ± 0.002 Å
• b: 18.843 ± 0.002 Å
• c: 17.127 ± 0.002 Å
• α: 90°
• β: 97.121 ± 0.008°
• γ: 90°
• Cell volume: 5446.6 ± 1.1 ų
• Cell temperature: 293.1 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.037
• Weighted residual factors for all reflections included in the refinement: 0.038
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No