Information card for entry 4074980

Structure parameters

• Common name: 10, [Pt2(L)(CO)2]
• Formula: C24 H12 N2 O2 Pt2
• Calculated formula: C24 H12 N2 O2 Pt2
• SMILES: c12ccc3c4c5c(ccc6c7c(cccc7)[Pt]3([n]56)C#[O])[Pt]([n]24)(C#[O])c2c1cccc2
• Title of publication: Dinuclear C,N,C Cyclometalated Platinum Derivatives with Bridging Delocalized Ligands. Fourfold Deprotonation of 6,6‘-Diphenyl-2,2‘-bipyridine, H4L, Promoted by “Pt(R)2” Fragments (R = Me, Ph). Crystal Structures of [Pt2(L)(3,5-Me2py)2] and {Pt2(L)(dppe)}2(dppe = 1,2-Bis(diphenylphosphino)ethane). X-ray Powder Diffraction of [Pt2(L)(CO)2]
• Authors of publication: Zucca, Antonio; Petretto, Giacomo Luigi; Stoccoro, Sergio; Cinellu, Maria Agostina; Minghetti, Giovanni; Manassero, Mario; Manassero, Carlo; Male, Louise; Albinati, Alberto
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 9
• Pages of publication: 2253
• a: 16.799 ± 0.0011 Å
• b: 16.799 Å
• c: 6.7283 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1898.77 ± 0.17 ų
• Cell temperature: 295 K
• Ambient diffraction temperature: 295 K
• Number of distinct elements: 5
• Space group number: 114
• Hermann-Mauguin space group symbol: P -4 21 c
• Hall space group symbol: P -4 2n
• RFsqd: 0.267
• Goodness-of-fit parameter for all reflections: 5.33
• Method of determination: powder diffraction
• Diffraction radiation type: Cu
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No