Information card for entry 4075186

Structure parameters

• Formula: C24 H28 O2 Si W
• Calculated formula: C24 H28 O2 Si W
• SMILES: [WH2]1234([SiH](c5ccccc5)c5ccccc5)(C#[O])(C#[O])[c]5([c]4([c]3([c]2([c]15C)C)C)C)C
• Title of publication: Synthesis, Structure, and Dynamic Behavior of Tungsten Dihydride Silyl Complexes Cp*(CO)2W(H)2(SiHPhR) (R = Ph, H, Cl)
• Authors of publication: Sakaba, Hiroyuki; Hirata, Takeshi; Kabuto, Chizuko; Kabuto, Kuninobu
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 21
• Pages of publication: 5145
• a: 10.086 ± 0.003 Å
• b: 10.642 ± 0.003 Å
• c: 11.511 ± 0.003 Å
• α: 74.631 ± 0.009°
• β: 87.934 ± 0.011°
• γ: 76.153 ± 0.009°
• Cell volume: 1156.2 ± 0.6 ų
• Cell temperature: 173.1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0207
• Weighted residual factors for all reflections included in the refinement: 0.058
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No