Information card for entry 4075456

Structure parameters

• Chemical name: bis{(m-h2-hydridodiethylsilyl)tetracarbonyl-molybdenum(I)}
• Formula: C16 H22 Mo2 O8 Si2
• Calculated formula: C16 H22 Mo2 O8 Si2
• SMILES: C(#[O])[Mo]12(C#[O])(C#[O])(C#[O])[Si]3(CC)(CC)[H][Mo]3(C#[O])(C#[O])(C#[O])(C#[O])[Si]2(CC)(CC)[H]1
• Title of publication: Photochemical Reaction of Mo(CO)6with Et2SiH2: Spectroscopic Characterization and Crystal Structure of the Bis{(μ-η2-hydridodiethylsilyl)tetracarbonylmolybdenum(I)} Complex [{Mo(μ-η2-H−SiEt2)(CO)4}2]
• Authors of publication: Stosur, Magdalena; Kochel, Andrzej; Keller, Antoni; Szymańska-Buzar, Teresa
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 15
• Pages of publication: 3791
• a: 9.1424 ± 0.0008 Å
• b: 10.0636 ± 0.0009 Å
• c: 14.1503 ± 0.0013 Å
• α: 90°
• β: 120.638 ± 0.006°
• γ: 90°
• Cell volume: 1120.16 ± 0.19 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0301
• Residual factor for significantly intense reflections: 0.0243
• Weighted residual factors for significantly intense reflections: 0.0552
• Weighted residual factors for all reflections included in the refinement: 0.057
• Goodness-of-fit parameter for all reflections included in the refinement: 1.1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No