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Information card for entry 4075775
Preview
Coordinates | 4075775.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C95 H77 B N4 O4 P4 Rh4 |
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Calculated formula | C95 H77 B N4 O4 P4 Rh4 |
SMILES | [Rh]1234([Rh]567([Rh]89([P](Cc%10[n]8n3c(c%10)C[P]2(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)([C]47([Rh]21([P](Cc1[n]2n6c(c1)C[P]5(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C#[O])=[CH]9c1ccc(cc1)C)C#[O])C#[O])C#[O].c1(ccccc1)[B-](c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M···M Interactions in [(μ-X)Rh2(PNNP)(CO)2]n+and [(μ4-X)Rh4(PNNP)2(CO)4]n+[X = H, O, C⋮C−R, R−C⋮C−R, C⋮C, CHCH2, SMe2;n= 0, 1: PNNP = 3,5-bis(diphenylphosphinomethyl)pyrazolato] |
Authors of publication | Tanaka, Shukichi; Dubs, Christian; Inagaki, Akiko; Akita, Munetaka |
Journal of publication | Organometallics |
Year of publication | 2005 |
Journal volume | 24 |
Journal issue | 1 |
Pages of publication | 163 |
a | 17.9746 ± 0.0003 Å |
b | 27.7046 ± 0.0006 Å |
c | 16.6001 ± 0.0003 Å |
α | 90° |
β | 90.846 ± 0.001° |
γ | 90° |
Cell volume | 8265.6 ± 0.3 Å3 |
Cell temperature | 213.2 K |
Number of distinct elements | 7 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/a 1 |
Hall space group symbol | -P 2yab |
Residual factor for significantly intense reflections | 0.0431 |
Weighted residual factors for all reflections included in the refinement | 0.127 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.687 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4075775.html
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