Information card for entry 4075801

Structure parameters

• Common name: 6
• Chemical name: Cyclohexyl-bis[N-(dimethylamino)pivaloimidato-N,O]siliconium chloride
• Formula: C23 H44 Cl10 N4 O2 Si
• Calculated formula: C23 H44 Cl10 N4 O2 Si
• Title of publication: Donor-Stabilized Silyl Cations. 9. Two Dissociation Patterns of Hexacoordinate Silicon Complexes: A Model Nucleophilic Substitution at Pentacoordinate Silicon1
• Authors of publication: Gostevskii, Boris; Silbert, Gilad; Adear, Keren; Sivaramakrishna, Akella; Stalke, Dietmar; Deuerlein, Stephan; Kocher, Nikolaus; Voronkov, Mikhail G.; Kalikhman, Inna; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 12
• Pages of publication: 2913
• a: 18.6709 ± 0.0011 Å
• b: 10.0493 ± 0.0006 Å
• c: 20.2826 ± 0.0012 Å
• α: 90°
• β: 100.508 ± 0.001°
• γ: 90°
• Cell volume: 3741.8 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0579
• Residual factor for significantly intense reflections: 0.0529
• Weighted residual factors for significantly intense reflections: 0.14
• Weighted residual factors for all reflections included in the refinement: 0.145
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No