Information card for entry 4076476

Structure parameters

• Formula: C32 H49 N Ru3
• Calculated formula: C32 H30 N Ru3
• Title of publication: Reactions of a Triruthenium Pentahydrido Complex with Imines Leading to the Formation of a Perpendicularly Coordinated Iminoacyl Ligand and the Scission of a C═N Bond on a Triruthenium Plane
• Authors of publication: Kanda, Hideyuki; Kawashima, Takashi; Takao, Toshiro; Suzuki, Hiroharu
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 5
• Pages of publication: 1917
• a: 11.0247 ± 0.0006 Å
• b: 11.0361 ± 0.0007 Å
• c: 14.8713 ± 0.0009 Å
• α: 106.4 ± 0.0016°
• β: 95.224 ± 0.0016°
• γ: 113.981 ± 0.0014°
• Cell volume: 1541.6 ± 0.16 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1164
• Residual factor for significantly intense reflections: 0.064
• Weighted residual factors for significantly intense reflections: 0.1393
• Weighted residual factors for all reflections included in the refinement: 0.1832
• Goodness-of-fit parameter for all reflections included in the refinement: 1.159
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No