Information card for entry 4076722

Structure parameters

• Common name: (dchpe)Pt(SiMe3)(CCPh)
• Formula: C37 H62 P2 Pt Si
• Calculated formula: C37 H62 P2 Pt Si
• SMILES: [Pt]1([Si](C)(C)C)([P](CC[P]1(C1CCCCC1)C1CCCCC1)(C1CCCCC1)C1CCCCC1)C#Cc1ccccc1
• Title of publication: Thermal and Photochemical Silicon−Carbon Bond Activation in Donor-Stabilized Platinum(0)−Alkyne Complexes
• Authors of publication: Müller, Christian; Lachicotte, Rene J.; Jones, William D.
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 6
• Pages of publication: 1190
• a: 11.6703 ± 0.0007 Å
• b: 20.3841 ± 0.0012 Å
• c: 17.0001 ± 0.001 Å
• α: 90°
• β: 110.075 ± 0.001°
• γ: 90°
• Cell volume: 3798.4 ± 0.4 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0464
• Residual factor for significantly intense reflections: 0.0427
• Weighted residual factors for significantly intense reflections: 0.0633
• Weighted residual factors for all reflections included in the refinement: 0.0639
• Goodness-of-fit parameter for all reflections included in the refinement: 1.556
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No