Information card for entry 4076775

Structure parameters

• Formula: C33 H38 O4 Ru2 Si2
• Calculated formula: C33 H38 O4 Ru2 Si2
• SMILES: [Ru]12([Si](C)(C)c3ccccc3)(C3([CH]1=[C]2(C[C@@H]([c]1([Ru]2456([Si](C)(C)c1ccccc1)(C#[O])C#[O])[c]53[cH]6[cH]2[cH]14)C)C)C)(C#[O])C#[O]
• Title of publication: Oxidative Addition of H−SiR3to Di- and Triruthenium Carbonyl Complexes Bearing a Bridging Azulene Ligand: Isolation of New Silylruthenium Complexes and Catalytic Hydrosilylation of Ketones
• Authors of publication: Matsubara, Kouki; Ryu, Kazuhiro; Maki, Tomoyuki; Iura, Takafumi; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 14
• Pages of publication: 3023
• a: 16.701 ± 0.004 Å
• b: 20.811 ± 0.015 Å
• c: 9.5303 ± 0.0019 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3312 ± 3 ų
• Cell temperature: 296.2 K
• Ambient diffraction temperature: 296.2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.1329
• Residual factor for significantly intense reflections: 0.0588
• Weighted residual factors for significantly intense reflections: 0.0966
• Weighted residual factors for all reflections included in the refinement: 0.1152
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No