Information card for entry 4076793

Structure parameters

• Formula: C72 H50 F10 P4 Pt3
• Calculated formula: C72 H50 F10 P4 Pt3
• SMILES: [Pt]123([Pt]4([Pt]1([P]3(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[C]14=C(C(F)=C(F)C(=C1F)F)F)([P]2(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Synthesis of Mixed-Valence Platinum Triangulo Clusters [Pt3(μ-PPh2)2(μ-C6F5)(C6F5)(PPh2R)2] (R = Ph, Me, Et). Crystal Structures of [Pt3(μ-PPh2)2(μ-C6F5)(C6F5)(PPh3)2] and [Pt3(μ-AgOClO3)(μ-PPh2)2(μ-C6F5)(C6F5)(PPh3)2]†
• Authors of publication: Falvello, Larry R.; Forniés, Juan; Fortuño, Consuelo; Durán, Fernando; Martín, Antonio
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 11
• Pages of publication: 2226
• a: 12.822 ± 0.002 Å
• b: 15.606 ± 0.002 Å
• c: 16.845 ± 0.002 Å
• α: 102.77 ± 0.02°
• β: 98.72 ± 0.02°
• γ: 105.16 ± 0.02°
• Cell volume: 3093.4 ± 0.9 ų
• Cell temperature: 297 ± 2 K
• Ambient diffraction temperature: 297 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0765
• Residual factor for significantly intense reflections: 0.0403
• Weighted residual factors for all reflections: 0.0901
• Weighted residual factors for significantly intense reflections: 0.0766
• Goodness-of-fit parameter for all reflections: 1.014
• Goodness-of-fit parameter for significantly intense reflections: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No